Intro

Hello everyone,

Today we cover entropy and the heat death of the universe.

The previous chapters can be found here and here. While I recommend you read both, you should at least read the first part and skim the second.

A collection of all topics covered can be found here: https://tildes.net/~tildes/8al/.

Subject

Intro

Entropy describes how chaotic a system is. In thermodynamics, chaos is created from an irreversible process. We are all sort of familiar with this concept. A broken cup will not unshatter itself. As a consequence of how our universe works, (net) chaos can only increase. And this might have far reaching consequence, if we look at the effects of entropy on a cosmic scale.

Entropy

Entropy describes an amount of irreversible chaos.

But first, let's cover cycles super quickly. In thermodynamics, a very important concept is a "cycle". A cycle is a repeating process, that returns to its initial condition. For instance, when we ride a bike. We're turning our feet around the crank shaft. Repeatedly returning to the same position we started from. As we push on the pedal, some of our work is lost and turned into heat. Primarily due to friction from the wheels and from the different mechanical parts.

A cycle that wastes no energy is called a reversible cycle. That would mean 100% of the work in a cycle (even the work that is turned to heat) has to be returned in some way to its original state. The most famous example of this is the Carnot heat engine.[1] But in reality, the Carnot heat engine is nothing more than a theoretical engine. As we remember from before, we cannot turn 100% of heat back into work. So any heat engine, be it a car's motor, a refrigerator, a star, or the human body, will in some way contribute to this irreversible chaos.

Now what about entropy? If we look at entropy at the molecular level, it all becomes a bit abstract. But we can think of this concept with bigger building blocks than molecules, and still be close enough. Say you have a brick house with orderly layed bricks. This house would love to come crashing down. And lets imagine it does. When the house lays in ruins, it is not likely to suddenly "fall" into the shape of the house again. So if the house has collapsed, our system is in a higher state of chaos. Our entropy has increased. And unless we supply work to the system (and waste energy trough heat), we will not get the brick house back.

So now we understand, that on the grand scale of the universe, entropy will only increase.

The heat death of the universe

But what are the consequences of this? Imagine entropy going on for billions and billions of years. Everything in the universe slowly reaching a higher state of chaos. Everything that is orderly, turns into chaos. All high quality energy has turned into low quality energy. Everything has been wasted and turned into heat. Everything ripped apart until you are left with nothing to rip apart. At this point, there is no interactions between molecules any more. Everything has reached absolute zero temperature.

At this point, entropy is at its absolute maximum. And we have reached entropic equilibrium.

This is the heat death of the universe.

Afterword

Of course, the heat death of the universe is just one of the many theories about the end of the universe. It assumes that thermodynamics properly describes the universe, and that there are no hidden surprises.

Frankly told, it's the best bet we have with our current knowledge. But we still know so little. So I would not panic just yet. Alternatively, this is where we could continue with "an engineer's perspective on existensial nihilism". But I think that this is something better reserved for later, and better presented by someone else.

We have covered what I consider the absolute minimum of thermodynamics, that still gives us a basic understanding of thermodynamics. There are of course a lot of other topics we could cover, but thats it for now. I will potentially write an appendix later with some questions or things that have been asked.

But for now, that's it. Questions, feedback or otherwise?

Notes

[1] The Carnot heat cycle is a bit beyond the level of what we have discussed so far. It describes a system where heat is supplied and removed to have a piston expand and contract without any energy becoming waste heat.

Introduction

I want to give an introduction on several physics topics at a level understandable to laypeople (high school level physics background). Making physics accessible to laypeople is a much discussed topic at universities. It can be very hard to translate the professional terms into a language understandable by people outside the field. So I will take this opportunity to challenge myself to (hopefully) create an understandable introduction to interesting topics in modern physics. To this end, I will take liberties in explaining things, and not always go for full scientific accuracy, while hopefully still getting the core concepts across. If a more in-depth explanation is wanted, please ask in the comments and I will do my best to answer.

Previous topics

Bookmarkable meta post with links to all previous topics

Today's topic

Today's topic is the dual nature of light and matter, the wave-particle duality. It is a central concept in quantum mechanics that - as is tradition - violates common sense. I will first discuss the duality for light and then, in the next post, for matter.

The dual nature of light

In what terms can we think of light so that its behaviour becomes understandable to us? As waves? Or as particles? There are arguments to be made for both. Let's look at what phenomena we can explain if we treat light as a wave.

The wave nature of light

Let's start with an analogy. Drop two stones in a pond, imagine what happens to the ripples in the pond when they meet each other. They will interact, when two troughs meet they amplify each other, forming a deeper trough. When two crests meet they do the same. When a crest and a trough meet they cancel out.

Now if we shine light through two small openings and observe the resulting pattern, we see it's just like ripples in a pond, forming an interference pattern. When looking at the pattern formed on a screen placed at some distance from the openings, we see a striped pattern Light can be described as an electromagnetic wave, with crests and troughs. It sure seems like light is wavey! The wave nature of light allows us to describe phenomena like refraction and diffraction.

The particle nature of light

When we shine light on some metals, they will start tossing out electrons. This is called the photoelectric effect. How can we understand this process? Well we know light is a wave, so we imagine that the wave crashes into the electron that is chilling out near the surface of the metal. Once the electron has absorbed enough of the light's energy it will be able to overcome the attractive forces between itself and the positively charged atom core (remember, an electron has negative charge and so is attracted to the atom cores). So a higher intensity of light should make the electron absorb the required amount of energy more quickly. Easy, done!

However, there's something very peculiar going on with the photoelectric effect. If we shine low frequency light on said metal, no matter how intense the light, not a single electron will emerge. Meanwhile if we shine very little high frequency light on the metal, no matter how low the intensity, the electron will emerge. But how can this be? A higher intensity of light should mean the electron is receiving more energy. Why does frequency enter into this?

It seems that the electron needs a single solid punch in order to escape the metal. In other words, it seems it needs to be hit by something like a microscopic billiard ball that will punch it out of the metal in one go. The way physicists understand this is by saying light is made up out of particles called photons, and that the energy a photon carries is linked to its frequency. So, now we can understand the photoelectric effect! When the frequency is high enough, the photons in the light beam all individually carry enough energy to convince an electron to leave the metal. When the frequency is too low, none of the photons individually can knock an electron out of the metal. So even if we fire a single photon, with high enough frequency, at the metal we will see one electron emerging. If we shine low frequency light with a super high intensity at the metal, not a single photon will emerge.

So there you have it! Light is made out of particles. Wait, what? You just told us it's made out of electromagnetic waves!

The wave-particle duality of light

So, maybe light is just particles and the wave are some sort of emerging behaviour? This was a popular idea, one that Einstein held for some time. Remember the experiment where we shone light through two small openings and saw interference (commonly known as the double slit experiment)? Let's just take a single photon and shoot it at the openings! Because light is particles we'll see the photon just goes through either opening - like a particle would. Then all the non-believers will have to admit light is made out of particles! However, when we do the experiment we see the photon interfere with itself, like it was a wave. Remember this picture which we said was due to wave interference of light? When a single photon goes through the openings, it will land somewhere on the screen, but it can only ever land in an area where the light waves wouldn't cancel out. If we shoot a bunch of photons through the openings one at a time, we will see that the photons create the same pattern as the one we said is due to wave interference!

Implications

So it would seem light acts like a particle in some cases, but it acts like a wave in some others. Let's take a step back and question these results. Why are we trying to fit light into either description? Just because it's convenient for us to think about things like waves and particles - we understand them intuitively. But really, there is no reason nature needs to behave in ways we find easy to understand. Why can't a photon be a bit wavey and a bit particley at the same time? Is it really that weird, or is it just our intuition being confused by this world we have no intuitive experience with? I would love to hear your opinions in the comments!

Observing photons

To add one final helping of crazy to this story; if we measure the photon's location right after it emerges from the slit we find that it doesn't interfere with itself and that it just went through a single slit. This links back to my previous post where I described superpositions in quantum mechanics. By observing the photon at the slits, we collapsed its superposition and it will behave as if it's really located at one spot, instead of being somehow spread out like a wave and interacting with itself. The self interaction is a result of its wavefunction interacting with itself, a concept that I will explain in the next post.

Conclusion

We learned that light cannot be described fully by treating it simply as a wave or simply as a bunch of particles. It seems to be a bit of both - but neither - at the same time. This forces us to abandon our intuition and accept that the quantum world is just fundamentally different from our every day life.

Next time

Next time we will talk about the dual nature of matter and try to unify the wave and particle descriptions through a concept known as the wavefunction.

Feedback

As usual, please let me know where I missed the mark. Also let me know if things are not clear to you, I will try to explain further in the comments!

Addendum

The photoelectric effect is actually what gave Einstein his Nobel prize! Although he is famous for his work on relativity theory he was very influential in the development of quantum mechanics too.